X-RAY
X – Rays are electromagnetic waves of short wavelength in the range of 10A° to 0.5
The discovery of X – rays goes to 1895 when W. Roentgen discovered while working with a discharge tube. He found that when the pressure in the discharge tube was reduced to about 10-3mm of Hg and the electric discharge was passed between the cathode and anode, the glass wall of the discharge tube behind the cathode began to glow with greenish yellow color. He also observed that a surface coated with barium platinum cyanide placed outside the discharge tube emitted light even when it was shielded from direct visible and ultraviolet light emitted by the discharge tube. After performing a series of experiment, Roentgen concluded that highly penetrating radiation of unknown nature are produced when a beam of fast moving electrons strikes a solid target such as tungsten. He named these radiations X – rays which led to the discovery of X – rays. Diagram of X – ray tube is:
Fig:
Different between X-ray and Ordinary light:
Ordinary light
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x-ray
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These are visible
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These are invisible
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They have heating effect
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They have no heating effect
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The wavelength of ordinary light range from 4 x 10-7m to 7.6 x 10-7m.
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The wavelength of x-ray range from 10-9m to 10-12m.
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It does not have high penetrating power. Ordinary light penetrates only transparent substance not opaque.
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They have high penetrating power and power of transparency for opaque substance
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The important properties of X – rays are:
(i) The X – rays are the electromagnetic wave of wavelength 10A° to 0.5°
(ii) The X – ray travels in vacuum with the speed of light ie. 3 * 108m/s.
(iii) They affect high penetrating power.
(iv) They have photographic effect.
(v) They are not deflected by electric and magnetic field.
X-rays are produced by the two methods
a. When fast moving electron having sufficient energy strikes the metal surface of high atomic number,it knock out the some electron from the inner orbit of the target metal due to vacancies are created so, to fill the vacant space electron from the higher energy level jump into these spaces emitting the radiation whose energy is equal to the difference in the energy of two orbits .thus obtained radiations by the heavy metals are X –rays.
b. When the fast moving electron strike the target they are heavily retarded by the coulomb repulsive force due to the charges of the electron of the atom .As a result retarding energy emits the radiation called X-rays.
Bragg’s law:
Statement: when a monochromatic X-rays impinge upon the atom in the crystal lattice, each atom acts as source of scattering radiation of the same wavelength. The crystal acts as a series of parallel reflecting plane. Then the intensity of the reflected beam at certain angle will be maximum when the path difference between two reflected waves from two different planes is an integral multiple of λ
Explanation of law:
Let us consider a set of parallel plane of atom point at a spacing d between the successive plates. Let a narrow monochromatic X-ray beam of wavelength λ be incident on the first plane at a glance angle ɵ consider the ray PQ incident on the first plane. The corresponding reflected ray QR must be also be incident at the same angle ɵ to the plane. Since X-ray are must more penetrating then that of ordinary light there is only partial reflected at each plane The complete absorption take place only after penetrating several layers. Consider two parallel rays PQR and P’Q’R’ in the beam which reflected by two atom Q and Q’. is vertically below Q. the ray P’Q’R’ has longer path than the ray PQR, To compute the path difference between the two rays from Q draw normal QT and QS on P’Q’ and Q’R’ respectively. Then the path difference =TQ’ +Q’S=d sinɵ +d sinɵ= 2dsinɵ
Hence the two ray will reinforce each other and produce maximum intensity, if
2dsinɵ=nλ where n=1, 2, 3, 4,……………
The integer n gives the order of the scattered beam; λ is the length of X-ray used. This equation is called bragg’s law
It is originated when the fast moving electron strike the target, they are heavily retarded. As the electrons go on being retorted continuously, the frequency of radiation emitted also goes on changing continuously. Hence, continuous X-rays are obtained.
The characteristics spectrum of X – rays origin is explained using Bohr’s postulate i.e. when an electron jumps from higher shell to lower, it emits energy in the form of radiation. So, when the fast moving electron strikes a metal target having high atomic number the electrons can knock out electrons from the inner shells of the atom, thus creating vacant spaces for its origination.
Some of the features of continuous spectrum of X – rays are:
(i) It consists of all possible wave length within a range.
(ii) The value of maximum intensity increases as potential increases.
Some of the features of characteristics X – ray are:
(i) The line of characteristics X – ray spectra occurs in various groups.
(ii) For each target material, there is minimum potential below which there is no radiation.
Production of X-rays:
X-rays are produce when fast moving electron are suddenly stopped by a solid target. A Coolidge tube is shown in figure.
Figure:
The tube is exhausted to the beast possible vacuum of the order of 10-5mm of Hg. The cathode consist of a tungsten filament (F) heated by a low tension battery. Thermionic electrons emitted by the filament are accelerated toward the target (T) by high P.D. maintained between F and T. the filament is placed inside a metal cup G to focus the electrons on the target. The target must be cooled to remove the heat generated in it by continuous electron- bombardment. The usual method is to mount the target material on a hollow copper tube through which cold water is continuously circulated. The target is made of material like tungsten or molybdenum having a high m.p. and high atomic no. metal with atomic no. give more energetic and intense X-rays when used as target. In the Coolidge tube the intensity and frequency of x-ray can be easily controlled.
The intensity of X-ray is depending upon the no. of electrons striking the target per second. The no. of the electrons give out by filament is directly propatational to its temperature, which can adjust by varying the current in the filament circuit. Therefore the intensity of X-ray varies with the filament current.
The frequency of X-ray emitted depends on the voltage between cathode and anode .let V be the accelerating potential across the tube. If e be the charge on the the electron the the work done on the electron in moving from cathode to anticathode is eV. Then the electron thus gain K.E. which is converted into x-ray when the electron strikes the target.
If υmaxbe the maximum frequencies of the x-ray produce
Then h υmax=eV
or, hC/λmin=eV
or, λmin=hC/eV where C= velocity of light and h= plank’s constant .
Crystal diffraction
Let us consider a set of parallel plane of atom point at a spacing d between the successive plates. Let a narrow monochromatic X-ray beam of wavelength λ be incident on the first plane at a glance angle ɵ .consider the ray PQ incident on the first plane. The corresponding reflected ray QR must be also be incident at the same angle ɵ to the plane. Since X-ray are must more penetrating then that of ordinary light there is only partial reflected at each plane, The complete absorption take place only after penetrating several layers. Consider two parallel rays PQR and P’Q’R’ in the beam which reflected by two atom Q and Q’. is vertically below Q. the ray P’Q’R’ has longer path than the ray PQR, To compute the path difference between the two rays from Q draw normal QT and QS on P’Q’ and Q’R’ respectively. Then the path difference =TQ’ +Q’S=d sinɵ +d sinɵ = 2dsinɵ
Hence the two ray will reinforce each other and produce maximum intensity, if
2dsinɵ=nλ where n=1, 2, 3, 4,
The integer n gives the order of the scattered beam; λ is the length of X-ray used. This equation is called Bragg’s law.
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